L.E. Shea, J.M. McKittrick, O.A. Lopez, and E. Sluzky, "Effect of Processing Parameters on Luminescence of Combustion-Synthesized, Rare Earth Activated Y3Al5O12 Phosphors," Ceramic Transactions, 67 (1996) 105-108.
A novel ceramic synthesis technique, combustion synthesis, was explored to produce Y3Al5O12 (YAG) phosphors
with improved physical and luminescent properties. The rare-earth ions Eu3+, Tb3+, and Tm3+ were used as activators
for red, green, and blue emission, respectively. The combustion synthesis technique involves the reaction of metal
nitrates (oxidizers) and an organic fuel at 500°C. Resulting powders are well-crystallized, with small particle size. Luminous
intensity was observed using photoluminescence measurements. The effects of processing parameters such as type
of fuel, ignition temperature, and an activator concentration were studied. Particle sizes were found to range
from 0.4 to 3 micrometers, depending upon the processing parameters. |