O.A. Lopez, J.M. McKittrick, and L.E. Shea, "Fluorescence Properties of Polycrystalline Tm3+ Activated Y3Al5O12 and Tm3+-Li+ Co-Activated Y3Al5O12 in the Visible and Near IR Ranges," Journal of Luminescence, 71 [1] 1-11 (1997).
The photoemission properties of polycrystalline powder Tm3+ - activated Y3Al5O12 and Tm3+-Li+ co-activated Y3Al5O12
were studied in the visible and near IR ranges at 300 K. The polycrystalline materials were obtained through a novel
combustion synthesis technique that yields chemically homogeneous and small particle size (<3.0 micrometer) powders. The
emission properties of Tm3+ - activated Y3Al5O12 showed that the intensity of the blue emission is weak compared
to the red emission. With the addition of Li+ as a co-activator, the intensity of the blue emission increased
by as much as 87%; however the red and IR emissions also increased. Efficiency measurements showed that the phosphor
reached a maximum of 0.21 lm/W at a voltage of 11.7 kV and current of 1 mA/cm2. The optimal composition for maximum
blue emission was found to be Y2.93Tm0.07Al5O12 doped with 1.0 at.% Li. |